When publishing for CD, Presenter generates a Launch_Presentation.exe file which launches the published presentation. .EXE files are not compatible with mac, which means that a presentation published for CD will not launch automatically from a CD.
You can automatically launch a presentation published for CD on a Windows PC or in a virtual Windows environment on a Mac (for example: Bootcamp, VMWare, or Parallels).
You may also launch the presentation on a Mac by double-clicking the player.html file on the CD. For the content to work as expected you will need to adjust your Flash Player security settings.